Product ID:E9 BATTERY (MERCURIC OXIDE-ZINC)
MSDS Date:03/19/1991
FSC:6135
NIIN:00-812-9039
MSDS Number: BPPCQ

EVEREADY BATTERY CO INC

CHECKERBOARD SQ
ST LOUIS, MO 63164
US

Emergency Phone: 417-625-3333, 1-800-526-4727

Info Phone: 216-835-7368

Cage: 83740

EVEREADY BATTERY CO INC

ST LOUIS, MO 63164 US

Telephone: 216-835-7368

Cage: 83740

MANGANESE DIOXIDE

CAS: 1313-13-9

RTECS: OP0350000

Fraction By Weight: 0-15%

OSHA PEL 5 MG MN/M3 CEILING

ACGIH TLV: 5 MG MN/M3

MERCURY (SARA III)

CAS: 7439-97-6

RTECS: OV4550000

Fraction By Weight: 0.3-1.5%

OSHA PEL S, C, 0.1 MG/M3

ACGIH TLV: S, 0.05 MG/M3; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

MERCURIC OXIDE (SARA III)

CAS: 21908-53-2

RTECS: OW8750000

Fraction By Weight: 20-50%

OSHA PEL 0.1 MG HG/M3;SKIN;C

ACGIH TLV: 0.1 MG HG/M3; 9293

POTASSIUM HYDROXIDE (SARA III)

CAS: 1310-58-3

RTECS: TT2100000

Fraction By Weight: 0-6%

OSHA PEL C, 2 MG/M3

ACGIH TLV: C 2 MG/M3; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SODIUM HYDROXIDE (SARA III)

CAS: 1310-73-2

RTECS: WB4900000

Fraction By Weight: 0-6%

OSHA PEL 2 MG/M3

ACGIH TLV: C 2 MG/M3; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ZINC (SARA III)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 5-15%

OSHA PEL 10 MG ZNO/M3

ACGIH TLV: 10 MG ZNO/M3; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE TO MERCURY-ACUTE:
SKIN:IRRITATION, ANURIA. EYE:IRRITATION, CORNEAL INJURY OR BURNS.
INGESTION:IMMEDIATE NECROSIS IN MOUTH, THROAT, ESOPHAGUS & STOMACH.
DEATH MAY OCCURE. INHALATION:DYSPNEA, C OUGH, FEVER, NAUSEA &
VOMITING, DIARRHEA, STOMATITIS, SALIVATION & METALLIC TASTE.
CHRONIC: CNS DISTURBANCES.
Explanation of Carcinogenicity:MERCURY, ZINC AND AMMONIUM CHLORIDE ARE
NOT LISTED BY IARC, NTP, OR OSHA AS CARCINOGENS.
Effects of Overexposure:TREMORS, CONVULSIONS & OTHER CNS DISTURBANCES,
PNEUMONITIS, CHEST PAINS, DYSPNEA, COUGHING, STOMATITIS, GINGIVITIS
AND LOOSENING OF TEETH, SALIVATION, LOSS OF MEMORY, METALLIC TASTE,
DIZZINESS, CLUMSI NESS, SLURRED SPEECH, DIARRHEA, PAIN & NUMBNESS
IN EXTREMITIES, NEPHRITIS, ANXIETY, HEADACHE, WEIGHT LOSS, AND
INSOMNIA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF
ALCOHOLISM, CHRONIC KIDNEY DISEASE OR KNOWN ALLERGY TO MERCURY MAY
BE AT INCREASED RISK FROM EXPOSURE TO MERCURY IF THE BATTERY IS
RUPTURED.

First Aid:IF EXPOSED TO RUPTURED BATTERY-INHALATION:REMOVE TO FRESH
AIR. IF NOT BREATHING GIVE CPR/OXYGEN. GET MEDICAL ATTENTION.
EYE:IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR 15 MINUTES. GET
MEDICAL ATTE NTION. SKIN: WASH SKIN WITH PLENTY OF SOAP & WATER.
INGESTION: GET IMMEDIATE MEDICAL ATTENTION.

Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS AND/OR MAY CAUSE
EXPLOSION.

Spill Release Procedures:PICK UP ALL BATTERIES. FOR A SMALL SPILL OF A
RUPTURED BATTERY: COLLECT THE DUST WITH A VACUUM CLEANER AND
DISPOSE OF BAG. WASH THE AREA.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM HEAT. STACK CARTONS NO MORE THAN 4 LAYERS HIGH ON A
PALLET AND NO MORE THAN 3 PALLETS HIGH.
Other Precautions:DO NOT SEAL BATTERIES IN AIR TIGHT OR WATERTIGHT
CONTAINERS OR COMPARTMENTS. DO NOT RUPTURE OR THROW BATTERIES IN
FIRE. DO NOT RECHARGE BATTERIES.

Respiratory Protection:NORMALLY NOT REQUIRED. WEAR MASK WHEN HANDLING
DUST FROM RUPTURED BATTERY.
Ventilation:GENERAL/LOCAL EXHAUST VENTILATION.
Protective Gloves:RUBBER, IF HANDLING RUPTURED BATTERY.
Eye Protection:NONE
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
THESE BATTERIES ARE MANUFACTURED "ARTICLES", WHICH DO NOT RESULT IN
EXPOSURE TO A HAZARDOUS CHEMICAL UNDER NORMAL CONDITIONS OF USE, AS
DEFINED IN OSHA HCS 1910.1200(C). WHEN HANDLING RUPTURED BATTERY
DO NOT GET ON SKIN, IN EYES OR ON CLOTHING. DO NOT BREATHE VAPORS.

HCC:N1
Appearance and Odor:CYLINDRICAL /D/
Percent Volatiles by Volume:NO

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS INCLUDE
TOXIC MERCURY VAPORS AND AMMONIUM CHLORIDE FUMES.

Waste Disposal Methods:DO NOT INCINERATE, BURY IN LANDFILL IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.